Increased Moisture Uptake of NCM622 Cathodes after Calendering due to Particle Breakage

نویسندگان

چکیده

As moisture presents a critical contamination in lithium-ion batteries (LIBs), electrodes and separators need to be post-dried before cell assembly. The adsorption, desorption re-adsorption of during processing is strongly dependent on their material system, manufacturing route microstructure. microstructure, turn, significantly defined by the coating density, which adjusted calendering. consequence, calendering step expected directly influence sorption behavior electrodes. This why different densities structural properties content NCM622 cathodes was investigated this study. For increasing an detected Karl Fischer Titration measurements. SEM BET analyses showed amount particle breakage, accompanied rising surface area. Hence, increased uptake with higher density mainly caused area, results from cracking breakage Electrochemical analysis that active area leads good performance formation at low C-rates. However, reduced porosity impairs ionic conductivity causes capacity loss

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ژورنال

عنوان ژورنال: Journal of The Electrochemical Society

سال: 2021

ISSN: ['0013-4651', '1945-7111']

DOI: https://doi.org/10.1149/1945-7111/ac24bb